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研究生： 邱顯明
Chiu, Hsien-Ming
論文名稱： 氧化銅奈米板之製備
Synthesis of Two-Dimensional CuO Nanoplates
指導教授： 葉晨聖
Yeh, Chen-Sheng
學位類別： 碩士
Master
系所名稱： 理學院 - 化學系
Department of Chemistry
論文出版年： 2004
畢業學年度： 92
語文別： 中文
論文頁數： 85
中文關鍵詞： 氧化銅 、奈米板
外文關鍵詞： CuO, nanoplates
相關次數： 點閱：52  下載：3 
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    • 　　一種嶄新的方法成功地製備二維的氧化銅奈米板。首先，我們先利用1064nm Nd:YAG雷射製備出銅奈米粒子，然後，加入硝酸銀水溶液，在加熱的條件下進行反應，再經由CTAB分離純化得到氧化銅奈米板。
    　　
    　　同時，我們也改變不同的反應條件，如劑量、溫度、時間、保護劑，瞭解這些因素對於奈米板的影響，並藉此得到最佳化的生成條件－銅銀莫耳比5:1，在55℃溫度下反應一小時，並藉由UV-Vis、TEM、SEM、EDS和電子繞射來鑑定此奈米板的成分、型態以及晶格結構。
    　　
    　　此新型氧化銅奈米板在光電材料、半導體、催化、電化學電池等領域中均具有其發展的潛能。

    　　We have demonstrated a new strategy to synthesis two-dimensional CuO nanoplates. For the preparation of CuO nanoplates, Cu nanoparticles were prepared by using laser ablation of CuO powders immersed in 2-propanol under aerobic conditions. Subsequently, the CuO nanoplates were generated by reacting Cu nanoparticles with aqueous AgNO3 solution at moderate heating condition. We have used surfactant CTAB as assistance to separate CuO nanoplates from nanoparticles in solution. The preparation of CuO nanoplates was studied in several experimental factors, for example reactant amount, temperature, reaction time, and capping agent. The optimal condition was found in which the molar ratio of Cu/Ag was used at 5/1 and reaction temperature was operated at 55℃ for 1 hour reaction. The TEM, SEM, EDS, and electron diffraction were employed to characterize composition, morphology, and structure for CuO nanoplates.

    　　The newly developed CuO nanoplates might have potential application in many subjects, such as optical devices, catalysis, and electrochemical cells.

    目錄.............................................................I 表目錄..........................................................IV 圖目錄...........................................................V 中文摘要.......................................................VII 英文摘要......................................................VIII 第一章 緒論......................................................1 1.1 奈米技術與奈米材料...........................................1 1.2 奈米粒子的特性...............................................5 1.2.1 量子尺寸效應(Quantum Size Effect)........................5 1.2.2 小尺寸效應 ..............................................6 1.2.3 表面效應.................................................7 1.2.4 宏觀量子穿隧效應.........................................7 1.2.5 庫侖堵塞效應.............................................8 1.3 奈米粒子之製備..............................................12 1.3.1 由大到小的方法(Top-Down)................................12 1.3.2 由小到大的方法(Bottom-Up)...............................14 1.4 銅奈米粒子簡介..............................................20 1.5 二維奈米材料簡介............................................22 1.5.1 自組裝(Self-Assembled)和模板(Template)技術..............22 1.5.2 異向性成長(Anisotropic Growth)技術......................23 第二章 基礎理論.................................................26 2.1 膠體粒子的穩定..............................................26 2.1.1 DLVO位能理論............................................28 2.2 金屬奈米粒子的光學性質......................................37 第三章 實驗部分.................................................43 3.1 研究動機與目的..............................................43 3.2 實驗藥品與儀器..............................................44 3.2.1 藥品....................................................44 3.2.2 儀器....................................................44 3.3 實驗步驟....................................................47 3.3.1 製備銅奈米粒子..........................................47 3.3.2 製備奈米板..............................................47 3.3.3 方形奈米板和圓形奈米粒子的分離..........................48 第四章 結果和討論...............................................51 4.1製備銅奈米粒子...............................................51 4.1.1 UV-Vis分析..............................................51 4.1.2 TEM分析.................................................51 4.1.3 Film-XRD分析............................................52 4.2製備奈米板...................................................53 4.2.1 劑量變因................................................55 4.2.2 溫度變因................................................55 4.2.3 時間變因................................................56 4.2.4 保護劑變因..............................................57 4.2.5 對照實驗................................................58 4.3 圓形奈米粒子和方形奈米板之結構鑑定..........................60 4.3.1圓形奈米粒子之鑑定.......................................60 4.3.2方形奈米板之鑑定.........................................61 4.4 反應機制的探討..............................................63 第五章 結語.....................................................78 參考文獻........................................................79

    1.Y. Xia, B. Gates, Y. Yin, Y. Lu, Adv. Mater., 2000, 12, 693
    2.R. Kubo, J. Phys. Soc. Jpn., 1962, 17, 975
    3.A. Kawabata, R. Kubo, J. Phys. Soc. Jpn., 1966, 21, 1765
    4.A. P. Alivisatos, Science, 1996, 271, 933
    5.張立德、牟季美著, “奈米材料和奈米結構”, 滄海書局, 民91
    6.(a) C. J. Murphy, N. R. Jana, Adv. Mater., 2002, 14, 80 (b) M. A. El-Sayed, Acc. Chem. Res., 2001, 34, 257
    7.莊萬發著, “超微粒子理論與應用”, 復漢出版社, 1994
    8.A. C. Shi, R. I. Masel, J. Catal., 1989, 120, 421 (b) L. M. Falicov, G. A. Somorjai, Proc. Natl. Acad. Sci. U.S.A., 1985, 82, 2207
    9.林鴻明、林中魁, “奈米科技應用研究與展望”, 工業材料, 179期, 84
    10.Y. Shigeki, K. Susumu, U. Ryozi, Jpn. J. Appl. Phys., 1973, 12, 1675
    11.Y. Kimura, Takeuchi, T. Ida, J. Phys. Chem., 1997, 101, 1322
    12.K. Kimura, Bull. Chem. Soc. Jpn., 1984, 57, 1683
    13.郭靖癸、黃俊傑、牟中原, “金屬奈米粒子的製造”, 物理雙月刊, 23卷, 6期
    14.T. G. Dietz, M. A. Duncan, D. E. Powers, R. E. Smalley, Science, 1994, 266, 1218
    15.K. Keisaku, W. Nobuhiko, Jpn. J. Appl. Phys. , 1976, 15, 755
    16.K. Kimura, S. Bandow, Bull. Chem. Soc. Jpn., 1983, 56, 3578
    17.K. Kimura, Bull. Chem. Soc. Jpn., 1987, 60, 3093
    18.K. Kimura, N. Satoh, Bull. Chem. Soc. Jpn., 1989, 62, 17558
    19.Y. Xia, P. Yang, Y. Sun, Y. Wu, B. Mayers, B. Gates, Y. Yin, F. Kim, H. Yan, Adv. Mater., 2003, 15, 353
    20.P. Yang, J. H. Song, B. Messer, Chem. Eur. J., 2002, 6, 8
    21.H. W. Kroto, J. R. Heath, S. C. O’Brien, R. F. Curl & R. E. Smalley, Nature, 1985, 318, 162
    22.A. M. Morales, C. M. Lieber, Science, 1998, 279, 208
    23.T. Guo, P. Nikolaev, A. Thress, D. T. Colbert, R. E. Smalley, Chem. Phys. Lett. , 1995, 243, 49
    24.A. Fojik, A. Henglein, B. Bunsenges., Phys. Chem., 1993, 97, 252
    25.J. Neddersen, G. Chumanov, T. M. Cotton, Appl. Spectrosc., 1993, 47, 1959
    26.J. S. Jeon, C. S. Yeh, J. Chin. Chem. Soc., 1998, 45, 721
    27.K. T. Wu, Y. D. Yao, C. R. C. Wang, P. F. Chen, E. T. Yeh, J. App. Phys., 1999, 85, 5959
    28.(a) Y. H. Yeh, M. S. Yeh, Y. P. Lee, C. S. Yeh, Chem. Lett. , 1998, 1183 (b) M. S. Yeh, Y. S. Yang, Y. P. Lee, H. F. Lee, Y. H. Yeh, C. S. Yeh, J. Phys. Chem. B, 1999, 103, 6851
    29.F. Mafuné, J. Y. Kohno, Y. Takeda, T. Kondow , H. Sawabe, J. Phys. Chem. B, 2000, 104, 9111
    30.Y. H. Chen, C. S. Yeh, Chem. Commun., 2001, 371
    31.Y. H. Chen, Y. H. Tseng, C. S. Yeh, J. Mater. Chem., 2002, 14, 1419
    32.S. H. Tsai, Y. H. Liu, P. L. Wu, C. S. Yeh, J. Mater. Chem., 2003, 13, 978
    33.A. V. Kabanov, S. N. Namethkin, A. V. Levashov, K. Martinek, Biol. Memb., 1985, 2, 985
    34.H. M. Yamaki, K. Kusakabe, S. Morooka, J. Memb. Sci. , 1993, 85, 167
    35.蘇品書編撰, ”超微粒子材料技術”, 復漢出版社, 1989
    36.P. P. Edwards, D. A. Jefferson, B. F. G. Johnson, A. C. Curtis, D. G. duff, A. I. Kirkland, A. S. Wallace, J. Phys. Chem., 1988, 92, 2270
    37.S. Tadao, O. Kazumi, I. Hiroyuki, J. Coll. Inter. Sci., 1997, 193, 140
    38.P. Pileni, I. Lisiecki, J. Am. Chem. Soc., 1993, 115, 3887
    39.簡建興, ”利用雷射削磨方法生成銀毫微米粒子之研究”, 國立成大博碩士論文, 化學, 1998
    40.M. Otaki, N. Toshima, Chem. Lett. , 1990, 1, 489
    41.K. Esumi, K. Matsuhisa, K. Torigie, Langmuir, 1995, 11, 3285
    42.N. Toshima, T. Takahashi, H. Hirai, Chem. Lett., 1985, 1245
    43.(a) R. Taush-Treml, A. Henglein, J. Lilie, Phys. Chem., 1978, 82, 1335 (b) P. Mulvaney, A. Henglein, J. Phys. Chem. , 1977, 81, 556
    44.Y. Yoshiro, S. Tomoo, O. Masashi and H. Hiroshi, J. Chem. Soc. Faraday. Trans.Ⅰ, 1987, 83, 1559
    45.Y. WatanNbe, S-I. Fujita, T. Dohmaru, S. Taniguchi, Y. Nagata, J. Chem. Soc. Chem. Commum. , 1992, 1620
    46.A. Henglein, Ultrasonics, 1987, 25, 6
    47.N. A. Dhas, H. Cohen, A. Gredanken, J. Phys. Chem. B, 1997, 101, 6834
    48.M. Gutierrez, A. Henglein, Ultrasonics, 1989, 27, 259
    49.K. Keisaku, W. Nobuhiko, Jpn. J. Appl. Phys. , 1976, 15, 755
    50.M. T. Reetz, W. Helbig, J. Am. Chem. Soc., 1994, 106, 2473
    51.Y. Y. Yu, S. S. Chang, C. L. Lee, C. R. C. Wang, J. Phys. Chem. B, 1994, 101, 6661
    52.M. V. Kortenaar, Z. I. Kolar, F. D. Tichelaar, J. Phys. Chem. B, 1999, 103, 2054
    53.H. Freundlich, D. Striner, J. Chem. Soc., 1937, 1081
    54.D. G. Eadon, J. A. Creighton, J. Chem. Soc. Farady. Trans., 1991, 87, 3881
    55.I. Lisiecki, F. Billoudet, and M. P. Pileni, J. Phys. Chem. , 1996, 100, 4160
    56.Q. Limin, M. Jiming, S. ulin, J. Collo. Inter. Sci, 1997, 86, 498
    57.Z. Paszti, Z. E. Horvath, G. Peto, A. Karacs, L. Guczi, Appl. Surf. Sci, 1997, 109, 67
    58.N. A. Dhas, C. P. Raj, A. Gedanken, Chem. Mater., 1998, 10, 1446
    59.A. Henglein, J. Phys. Chem. B, 2000, 104, 1206
    60.G. Schimid, “ Clusters and Colloids”, From Theroy to Application, VCH：New York , 1994
    61.K. Uchida, S. Kaneko, S. Omi, C. Hata, H. Tanjy, Y. Asahara, and A. J. Ikushime, J. Opt. Soc. Am. B, 1994, 11, 1236
    62.H. Hosono, Y. Abe, Appl. Phys. Lett., 1992, 60, 2613
    63.H. H. Huang, F. Q. Yan, Y. M. Kek, C. H. Chew, G. Q. Xu, W. Ji, P. S. Oh, and S. H. Tang, Langmuir, 1997, 13, 172
    64.H. Hirai, Hidehiko, Wakabayshi, M. Komiyama, Chem. Lett, 1983, 1047
    65.H. Hirai, Hidehiko, Wakabayshi, M. Komiyama, Bull. Chem. Soc. Jpn., 1986, 59, 545
    66.S. M. Angel, L. F. Katz, D. D. Archibald, D. E. Honigs, App. Spectro., 1989, 43, 367
    67.(a) J. J. Mock, M. Barbic, D. R. Smith, D. A. Schultz, S. Schultz, J. Chem. Phys., 2002, 116, 6755 (b) K. Kneipp, Y. Wang, H. Kneipp, L. T. Perelman, I. Itzkan, R. R. Dasari, M. S. Feld, Phys. Rev. Lett., 2002, 116, 6755 (c) L. A. Dick, A. D. McFarland, C. L. Haynes, R. P. Van Duyne, J. Phys. Chem. B, 2002, 106, 853
    68.(a) A. J. Hurd, D. W. Schaefer, Phys. Rev. Lett., 1985, 54, 1043 (b) H. H. Wickman, J. N. Korley, Nature, 1998, 393, 445
    69.F. Lenzmann, K. Li, A. H. Kitai, H. D. H. Stover, Chem. Mater., 1994, 6, 156
    70.(a) N. D. Denkov, O. D. Velev, P. A. Kralchevsky, I. B. Ivanov, H. Yoshimura, K. Nagayama, Nature, 1993, 361, 26 (b) A. S. Dimitrov, K. Nagayama, Langmuir, 1996, 12, 1303 (c) A. S. Dimitrov, T. Miwa, K. Nagayama, Langmuir, 1999, 15, 5257
    71.P. Jiang, J. F. Bertone, K. S. Hwang, V. L. Colvin, Chem. Mater., 1999, 11, 2132
    72.(a) M. Trau, D. A. Saville, I. A. Aksay, Science, 1996, 272, 706 (b) M. Trau, D. A. Saville, I. A. Aksay, Langmuir, 1997, 13, 6375
    73.M. Giersig, P. Mulvaney, Langmuir, 1993, 9, 3408
    74.R. C. Jin, Y. W. Cao, C. A. Mirkin, K. L. Kelly, G. C. Schatz, J. G. Zheng, Science, 2001, 294, 1901
    75.(a) S. Chen, D. L. Carroll, Nano Lett., 2002, 2, 1003 (b) S. Chen, Z. Fan, D. L. Carroll, J. Phys. Chem. B, 2002, 106, 10777
    76.(a) Y. Sun, B. Mayers, Y. Xia, Nano Lett., 2003, 3, 675 (b) Y. Sun, Y. Xia, Adv. Mater., 2003, 15, 695
    77.J. S. Bradley, B. Tesche, W. Busser, M. Maase, M. T. Reetz, J. Am. Chem. Soc., 2000, 122, 4631
    78.I. Pastoriza-Santos, L. M. Liz-Marz´an, Nano Lett., 2002, 2, 903
    79.R. J. Hunter, “Introduction to Modern Colloid Science ” 1993
    80.(a) H. R. Kruyt, “Colloid Science”, Elsevier Science Publishing Company INC, 1952 (b)張有義、郭蘭生編譯, “膠體及界面化學入門”, 高立圖書有限公司, 1997
    81.R. J. Good, R. R. Stromberg, “Surface and Colloid Science Vol.11” , published by Plenum Press , New York and London.
    82.C. F. Bohren, D. R. Huffman, “Absorption and Scattering of Light by Small Particles”, Wiley-Interscience, 1988
    83.P. Mulvaney, Langmuir, 1996, 12, 788
    84.K. L. Kelly, E. Coronado, L. L. Zhao, G. C. Schatz, J. Phys. Chem. B, 2003, 107, 668
    85.U. Kreibig and M. Vollmer, “Optical Properties of Metal Cluster”, Vol. 25, Springer, Berlin, 1995
    86.(a) Y. Sun, Y. Xia, Science, 2002, 298, 2176 (b) Y. Sun, B. Mayers, Y. Xia, Nano Lett., 2002, 2, 481 (c) Y. Sun, B. Mayers, Y. Xia, Adv. Mater., 2003, 15, 641 (d) Y. Sun, Y. Xia, Anal. Chem., 2002, 74, 5297
    87.Y. Sun, Y. Xia, Nano Lett., 2003, 3, 1569
    88.J. Khatouri, M. Mostafavi, J. Amblard, J. Belloni, Chem. Phys. Lett. 1992, 191, 351
    89.N. R. Jana, Chem. Commun., 2003, 1950
    90.A. R. Roosen, W. C. Carter, Physica A, 1998, 261, 232
    91.Z. Zhang, B. Zhao, L. Hu, J. Solid State Chem., 1996, 121, 105
    92.(a) X. Peng, L. Manna, W. Yang, J. Wickham, E. Scher, A. Kadavanish, A. P. Alivisatos, Nature, 2000, 404, 59 (b) V. F. Puntes, K. M. Krishnan, A. P. Alivisatos, Science, 2001, 291, 2115
    93.Y. Y. Yu, S. S. Chang, C. L. Lee, C. R. C. Wang, J. Phys. Chem. B, 2003, 107, 2466
    94.Y. Sun, B. Mayers, T. Hericks, Y. Xia, Nano Lett., 2003, 3, 955
    95.C. L. Lee, C. C. Wan, Y. Y. Wang, Adv. Funct. Mater., 2001, 11, 344
    96.S. Ayyappan, R. S. Gopalan, G. N. Subbanna, C. N. R. Rao, J. Mater. Res., 1997, 12, 398
    97.(a) A. E. Rakhshani, Solid-State Electron., 1986, 29, 7 (b) X. Jiang, T. Herricks, Y. Xia, Nano Lett., 2002, 2, 1333

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