簡易檢索 / 詳目顯示

回結果列表
研究生： 許芳銜
Hsu, Fang-Hsien
論文名稱： 含鉛金屬配位高分子化合物的水熱合成及構造之研究
A Study on Hydrothermal Synthesis and Structures of the Lead(II) Coordination Polymers
指導教授： 許拱北
Shiu, Kom-Bei
學位類別： 碩士
Master
系所名稱： 理學院 - 化學系碩士在職專班
Department of Chemistry (on the job class)
論文出版年： 2006
畢業學年度： 94
語文別： 中文
論文頁數： 109
中文關鍵詞： 鉛金屬 、水熱合成
外文關鍵詞： Lead, Hydrothermal Synthesis
相關次數： 點閱：59  下載：1 
分享至:
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報

    • 摘要
    Pb(NO3)2與pyridinedicarboxylic acid經使用水熱合成法，合成出六種鉛金屬配位高分子化合物，包括: [Pb(2,3-pdc)]n (1), [Pb4(2,4-pdc)2(OH)4]n (2), [Pb(2,5-pdc)(H2O)]n (3), [Pb(2,6-pdc)]n (4), [Pb(3,4-pdc)(H2O)]n (5), {[Pb(3,5- pdc)(H2O)]．2H2O}n (6). 其中2~4和6為二維結構，1和5為三維結構。1~3含有孔洞；最大的孔洞發生在結構2，該孔洞大小為(約5Å × 4Å)。在這六種配位高分子化合物中，以6的熱穩定度最佳，可能與其具有特殊的結構有關。除單晶構造鑑定外，上述六種配位高分子化合物也使用元素分析、粉末X光繞射以及紅外線光譜來鑑定。

    Abstract
    The hydrothermal reaction of Pb(NO3)2 and pyridinedicarboxylic acid in the presence of bipyridine results in six novel compounds.
    Six novel organic-inorganic coordination polymers:[Pb(2,3-pdc)]n (1), [Pb4(2,4-pdc)2(OH)4]n (2), [Pb(2,5-pdc)(H2O)]n (3), [Pb(2,6-pdc)]n (4), [Pb(3,4-pdc)(H2O)]n (5), {[Pb(3,5- pdc)(H2O)]．2H2O}n (6).
    Compound (2),(3),(4)and(6) are 2-dimensional structures, with consideration of hydrogen bonding interactions, can be converted into 3-dimensional structures. Compound (1)and(5) are 3-dimensional structures. The (1),(2) and(3) structures contain cavities which were also measured.The new structures have been characterized by elemental analysis, FTIR spectroscopy, thermogavimetric analysis, powder X-ray diffractometer and single-crystal structures via X-ray diffraction data.

    目 錄 中英文摘要..........................................................................I 誌謝....................................................................................III 目錄....................................................................................IV 表目錄.................................................................................V 圖目錄................................................................................VI 第一章 緒論.........................................................................1 1.1 前言................................................................................1 1.2 水熱法原理與文獻回顧................................................3 1.3 研究動機......................................................................14 第二章 實驗.......................................................................15 2.1 實驗藥品與儀器 .........................................................15 2.2 實驗方法：水熱合成法..............................................19 2.3 高分子化合物合成......................................................21 第三章 結果與討論...........................................................27 3.1 [Pb(2,3-pdc)]n (1) 合成構造與鑑定.............................27 3.2 [Pb4(2,4-pdc)2(OH)4]n (2) 合成構造與鑑定...............34 3.3 [Pb(2,5-pdc)(H2O)]n (3) 合成構造與鑑定...................41 3.4 [Pb(2,6-pdc)]n (4) 合成構造與鑑定.............................48 3.5 [Pb(3,4-pdc)(H2O)]n (5) 合成構造與鑑定...................55 3.6 {[Pb(3,5-pdc)(H2O)]2H2O}n (6) 合成構造與鑑定..62 3.7 化合物之結果討論.......................................................70 第四章 結論........................................................................74 參考文獻(附錄)..................................................................75

    參考文獻

    1. Susumu Kitagawa, Ryo Kitaura , Angew. Chem. Int. Ed. , 2004,43,2334.
    2. Stuart L. James, Chem. Soc. Rev., 2003, 32,276.
    3. Russell, V. A.; Evans, C. C.; Li, W.; M. D. Science ,1997, 276, 575.
    4. Ranganathan, A,; Pedireddi, V. R.; Rao, C. N. R. J. J. Am. Chem. Soc. 1999, 121, 1752.
    5. D.J. Watson, C. A. Randall, et al. , Am. Ceram.Soc.Inc., 1988, 1, 154.
    6. Atkins, P. W. Physical Chemistry , 1994, 5th.
    7. Angew. Chem.Int.Ed. Engl.1985, 24, 1026.
    8. J.-H. Liao , Inorganic Chemistry Communications , 2004 , 7, 402.
    9. Jack Y. Lu* and Amy M. Babb., Chem. Commun., 2001, 821.
    10. Jack Y. Lu* and Amy M. Babb., Chem. Commun., 2003, 1346.
    11. Jack Y. Lu, Inorg. Chem. Comm., 2001, 4,716.
    12. Qiutian Liu, Eur. J. Inorg. Chem., 2004, 1454.
    13. Nobuo Okabe, Acta Cryst. , 1996, C52, 1610.
    14. Nobuo Okabe, Acta Cryst. , 1996, C52, 1410.
    15. Storr Alan, Thompson C. Robert , Polyhedron , 2003, 22, 3025.
    16. Soon W. Lee, Inorganic Chemistry Communications , 2002, 5, 978.
    17. Soon W. Lee, Inorganica Chimica Acta, 2001, 324, 293.
    18. Parimal K. Bharadwaj , Inorg. Chem., 2004, 43, 2293.
    19. Parimal K. Bharadwaj , Inorg. Chem., 2003, 42, 8250.
    20. Enbo Wang, Inorg. Chem., 2004, 43, 1850.
    21. Soon W. Lee, Inorg. Chem. Comm., 2001, 4, 297.
    22. Soon W. Lee, Inorg. Chem. Comm., 2002, 5, 978.
    23. Xu Haitao,Journal of Molecular Structure, 2002, 610, 47.
    24. K.A. Beveridge and G.W. Bushnell,Can.J.Chem., 1979, 57, 2984.
    25. K.J. Nordell et al. Polyhedron, 2004 , 23, 2161.
    26. 嚴佳宏,國立成功大學碩士論文, 2005, 27.
    27. Elsa E. Sileo, Journal of Molecular Structure, 2003, 644, 67.
    28. Alicia M. Beatty, Crystal Growth & Design, 2006, Vol. 6, No.1,122
    29. Nobuo Okabe,Acta Cryst., 2000, C56, 305
    30. Li-Li Wen, Inorganic Chemistry, 2005 ,44, 7161
    31. M. Rafizadeh , Acta Cryst., 2006, E62, m90.
    32. Guo-Qing Bian, Acta Cryst., 2004, C60, m338.
    33. Bin Zhao, Angew. Chem. Int. Ed., 2003, 42, 8.
    34. Tabatha Whitfield, Solid State Sciences , 2001, 3, 829.
    35. O’Keeffe, M., Yaghi O. M., Nature , 1999, 402, 276.
    36. Jarrod F. Eubank,Crystal Growth & Design, 2006, 6, 6.

    下載圖示 校內：2016-08-23公開
    校外：2016-08-23公開
    QR CODE