| 研究生: |
陳建維 Chen, Jian-Wei |
|---|---|
| 論文名稱: |
熱處理對含3.3%鈀球型牙科汞齊合金之影響 Effect of heat treatment on 3.3% Pd-containing spherical dental amalgam |
| 指導教授: |
朱建平
Ju, Chien-Ping 陳瑾惠 Chern Lin, Jiin-Huey |
| 學位類別: |
碩士 Master |
| 系所名稱: |
工學院 - 材料科學及工程學系 Department of Materials Science and Engineering |
| 論文出版年: | 2008 |
| 畢業學年度: | 96 |
| 語文別: | 中文 |
| 論文頁數: | 126 |
| 中文關鍵詞: | 汞齊合金 、汞釋出 |
| 外文關鍵詞: | Mercury release, Amalgam |
| 相關次數: | 點閱:58 下載:0 |
| 分享至: |
| 查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報 |
汞齊合金主要是以銀、銅與錫之合金粉末與汞混合而成的合金,有時也會添加少量金屬(如鋅、銦、鈀等)以改善其性質。在汞齊合金中添加微量的鈀,可改善汞齊合金的汞釋出率、機械性質、抗腐蝕性與抗潛變性。
本實驗選用自行配料,由美國HJE公司協助噴粉之AP3合金粉末,經過T1℃、T2℃、T3℃、T4℃、T5℃、T6℃,持溫兩天之熱處理,進行各項性質測試。本實驗目的在於:討論熱處理對AP3汞齊合金之影響與差異,選用AP3最佳之熱處理條件與不含鈀之球型AP0粉末混成MixP1及MixP2之雙成份汞齊合金,並與單成份汞齊合金AP1T5及AP2T5作比較,以設計出低汞蒸氣釋出率、操作性質、機械性質良好之汞齊合金為目的。
結果發現,AP3合金粉末在熱處理T3℃時有最佳之性質,添加適當的AP0合金粉末製成雙成份汞齊合金時,可以降低其汞釋出率及提升1小時之抗壓強度。選擇本實驗最佳之材料進行冷熱循環實驗,MixP1及MixP2仍保有良好的機械性質,且經細胞毒性測試後,本實驗所使用之汞齊合金皆不會對細胞造成毒性傷害。
Amalgam was mixed with mercury by the silver, copper and the tin powder. It’s properties can be improved by adding few metals like zinc, indium and palladium . Adding few palladium in amalgam can impove the amalgam’s mercury vapor release rate, mechanical properties, corrosion resistance and creep resistance.
This experiment selects voluntarily the ingredient AP3 which was powdered by way of American HJE Corporation, and then passes through T1℃,T2℃, T3℃, T4℃, T5℃, T6℃, hold the warm two days of heat treatments, and carries on each test. This experiment’s goal was focused on the influence of heat treatment on AP3 spherical amalgam , selects and mixs the AP3 power and AP0 powder of best heat treatment condition to make the double ingredient amalgam MixP1 and MixP2, and compared with the single ingredient amalgam AP1T5 and AP2T5. It’s the goal to design the amalgam which have low mercury vapor release rate, good operation and mechanical properties.
The result discovered that AP3 amalgam when it passed through T3℃ heat treatment has the best property, double ingredient amalgam may reduce its mercury release rate and have better 1 hour compressive strength when adding the suitable AP0 powder. It holds the good mechanical property while choosing the experiment’s best material MixP1 and MixP2 to carry on the thermal cycling test. After cytotoxicity test, all amalgam of this experiment will not cause the toxic damage to the cell.
第六章 參考文獻
Arcoria CJ, Fisher MA and Wagner MJ,“Microleakage in Alloy-Glass Ionomer Linked Amalgam Restorations after Thermalcycling”, Journal of Oral Rehabilitation 18:9-14, 1991.
Cannon M,S,, Kapes E,D,, Palkuti G,A, (1985). Dr Black and the “amalgam question”. J History Medicine 40:309-326.
Chern Lin JH, Chung KH, Marshall SJ and Greener EH,“The Role of Pd in Gamma 1 (Ag2Hg3) to Beta 1 (Ag-Hg) Transformation”, J Dent Res 66:111, Abst. 35, 1987a.
Chern Lin JH, Marshall SJ, Chung KH and Greener EH,“Structural Changes in Blending Amalgam Compositions with Pd Additions”, J Dent Res 66:201, Abst. 192, 1987b.
Chern Lin JH and Greener EH,“Microstructures of Pd-containing Dispersants for Admixed Dental Amalgams”, Dent Mater 7:254-257, 1991.
Chern Lin JH, Lee HC and Ju CP,“Effect of Addition of Palladium on properties of γ1(Ag2Hg3) Phase”, Biomaterials 18:1-8, 1997.
Chung KH, Chern Lin JH and Greener EH,“Effect of Pd Additions on Creep and Compressive Strength of Blend Amalgam(Abstract)”, J Dent Res65:192, Abst 22, 1986.
Colon P, Pradelle-Plasse N, Galland J,“Evalution of the long-term Corrosion Behavior of Dental Amalgams: Influence of Palladium Addition and Particle Morphology”, Dental Materials. 19(3):232-9, 2003 May.
Ferracane JL, Hanawa T, Okabe T(1992). Effectiveness of oxide films in reducing mercury release from amalgams. J Dent Res 71(5):1151-1155.
Ferracane JL, Nakajima H, Okabe T (1993). Enhanced evaporation of mercury from amalgams in non-oxidizing environments. Dent Mater 9:300-305.
Gale MS and Darvell BW,“Thermal Cycling Procedures for Laboratory Testing of Dental Restorations”, Journal of Dentistry 27:89-99, 1999.
Greener EH and Chung KH,“Properties of Ag-Cu-Pd Dispersed Phase Amalgam: Compressive Strength, Creep and Corrosion”, J Dent Res 61(10):1192-1194, 1982.
Greener EH , Chung KH and Chern Lin JH,“Creep in a Pd-enriched High-copper Amalgam”, Biomaterials 9:213-217, 1988.
Johnson LB(1970). Ag-Sn-Hg alloys as electron compounds. J Biomed Mater Res4:269-274.
Lee KH, Shin MC, Lee JY (1987).Amalgamation mechanism in dental amalgam alloys. J Mat Sci 22:3949-3955.
Mackert JR,“Dental Amalgam of mercury”, J Amer Dent Assoc 122:54-61, 1991.
Mahler DB, Adey JD and Van Eysden J,“Quantitative Microprobe Analysis of Amalgam”, J Dent Res 54:218-226, 1975.
Mahler DB, “In Dental Materials Review”,Dental amalgam ,Ann Arbor : Univ. of Michigan Press,1976
Mahler D.B. and Adey J.D.(1984).Microprobe analysis of three high-copper amalgams.J Dent. Res 63(3):921-925.
Mahler DB, Engle JH and Adey JD,“Effect of Pd on the Clinical Performance of Amalgam”, J Dent Res 69(1):1751-1759, 1990.
Mahler DB and Nelson LW,“Sensitivity Answers Sought in Amalgam Alloy Microleakage Study”, J Amer Dent Asso 125:282-288, 1994.
Mahler DB and Bryant RW,“Microleakage of Amalgam Alloys: An Update”, J Amer Dent Asso 127:1351-1356, 1996.
Mahler DB,“The High-copper Dental Amalgam Alloys”, J Dent Res76(1):537-541, 1997.
Malhotra ML (1976). Microstructure in gold-containing Ag3Sn-amalgam. J biomed Mater Res 10:9-23.
Mante F, Chern Lin JH, Greener EH and Moser J,“Palladium Effects on Thermal Expansion and Phase Changes in Dental Amalgam”, J Dent Res 67:308, Abst. 1536, 1988.
Mante F, Greener EH, Chern Lin JH and Gilbert JL,“Effect of Particle Configuration on Properties of Pd Containing Dental amalgam”, Northwestern dent Res 2(2):19-20, 1991.
Mante F.,Greener E.H.,Gilbert J.L., Chern Lin J.H.(1995).The effect of matrix phase morphology on the structure of Ag-Cu-Pd dispersed phase dental amalgam. J Oral Rehabil 22:711-715.
Marek M,“The Release of Mercury from Dental Amalgam: the Mechanism and In Vitro Testing ”,J Dent Res 69:1167-1174, 1990.
Moffett JC, Ryge G, Barkow AG (1952). Phase changes in silver-tin amalgams. J App Phy 23(10):1188-1189.
Okabe T, Mitchell R, Butts MB, Bosley JR, Faurhurst CW (1977). Analysis of Asgar-Mahler zone in Dispersalloy amalgam of electron diffraction. J Dent Res56:1037-1043
Omar IM, Chern Lin JH, Greener EH and Marshall SJ,“Solubility of Pd inγ1 and Its Effect on the γ1 toβ1 Transformation in Dental Amalgam”, Northwestern Dent Res 1:10-15, 1989.
Powell LV, Johnson GH and Bales DJ,“Effect of Admixed on Mercury Vapor Release from Dental Amalgam”, J Dent Res 68:1231-1233, 1989.
Psarras V, Derand T, Nilner K(1994). Effect of selenium om mercury vapour released from dental amalgams: An in vitro study. Swed Dent J 18:15-23.
Reynolds CL, Wawner FE ,Wilsdorf HGF (1974). In situ observation of crystal growth and mass transport in a scanning electron microscope as applied to amalgams. Scrip Met 8:657-660.
Ricker JB, Chern Lin JH and Greener EH,“Effect of Porosity on Compressive Strength of Palladium Amalgam”, J Dent Res 69:178, 1990.
Ring ME,“Dentistry. An Illustrated History”, Harry N Abrams, Inc. New york.
Youdelis WV, “Effect of indium on residual mercury content and compressive strength of amalgam “,J Canad Dent Assn 45(2):60-62, 1979
陳剛毅,“含鈀牙科汞齊合金之性質及微結構研究”,國立成功大學材料科學及工程學系博士論文, 1999.
陳玉萱,“熱處理Ag-Cu-Pd合金粉末對混合型含鈀汞齊合金性質之影響”, 國立成功大學材料科學及工程學系碩士論文, 2001.
蔡光任,”熱處理對單成分圓球型含鈀汞齊合金性質的影響”,國立成功大學材料科學及工程研究所碩士論文,2004
施宗佑, ”熱處理對單成份球型牙科汞齊合金性質影響之研究”,國立成功大學材料科學及工程研究所碩士論文,2005
校內:2107-07-30公開