近年來染料朝著抗光解、抗氧化等功能性發展，使得染料分子組成益趨複雜，因製造與使用過程中，染料可能會被釋放到環境中造成污染，故解決染料廢水問題乃重要的研究課題。電鍍污泥中富含銅、鋅、鎳、鉻、鐵等多種二價/三價金屬具鐵氧磁體化之潛勢，脫硫渣含有豐富元素鐵及鐵氧化物，兩者皆具有誘發類芬頓(Fenton-like)反應潛力。本研究利用脫硫渣及鐵氧磁體作為反應劑，探討其誘發H2O2產生Fenton-like反應處理反應黑染料(Reactive Black 5, RB5)之可行性，藉此提升脫硫渣及鐵氧磁體之資材化位階。

研究結果發現，當RB5濃度為50 mg/L時，無論以脫硫渣或鎳鐵氧磁體誘發Fenton-like反應處理RB5之合適條件皆為pH=2、H2O2濃度為60mg/L。以礦化效率而言，在反應時間達24小時，以NiFe2O4(63%)優於脫硫渣(23%)。在鐵氧磁體應用方面，當燒結溫度越高、持溫持間越長，合成之NiFe2O4晶相強度越高，對RB5之脫色及礦化效率越佳，其中以燒結溫度1000℃且持溫10小時為Fenton-like反應處理RB5之最適鐵氧磁體化條件。以電鍍污泥經鐵氧磁體化後粉體，進行Fenton-like反應1 小時後，RB5可完全脫色，且反應後溶液中重金屬僅溶出微量，可知高溫鐵氧磁體法不僅可有效穩定電鍍污泥中重金屬，燒成熟料更具有觸媒效果。

在材料穩健性試驗方面，以電鍍污泥合成之鐵氧磁體顆粒，利用Fenton-like反應處理RB5，即使經10次重複試驗，其去除RB5效果仍維持穩定，當反應時間達6 小時，RB5可完全脫色，且礦化效率高，反應過程中僅少量Fe溶出。而脫硫渣對RB5之脫色效率略低於電鍍污泥合成之鐵氧磁體，其礦化效率則隨著重複試驗次數增加而降低，且脫硫渣中Fe於試驗中大量溶出。綜合而言，脫硫渣及電鍍污泥合成之鐵氧磁體皆具有良好的Fenton-like觸媒效果，為環境友善之再生觸媒。因脫硫渣Fe大量釋出，反應速率快，建議應用於批次處理。而電鍍污泥合成之鐵氧磁體於反應過程中穩定，Fe幾乎不溶，具有作為透水性催化牆材料潛力，建議可應用於現地長期性處理污染物。

The functional development of dye, such as anti-photolysis and anti-oxidation, increased the complexity of dye molecule composition in recent years. During the manufacturing process, dye may be released to the environment and causes pollution, therefore solving the problem of dye polluted wastewater is an important research topic. Electroplating sludge (EPS) is rich in copper, zinc, nickel, chromium, iron and other divalent / trivalent metals that contribute to its potential for ferrite synthesis; while desulfurization slag (DS slag) contains sufficient iron and iron oxides. Both EPS and DS slag have the potential to induce Fenton-like reaction. In this study, DS slag and ferrite were used as reactant to investigate their inductivity on H2O2 to generate Fenton-like reaction together with their feasibility on Reactive Black 5 (RB5) degradation so as to enhance the status of DS slag and ferrite in the field of materialization.

Results showed with 50 mg/L concentration of RB5, regardless of using DS slag or nickel ferrite induced H2O2 to generate Fenton-like reaction on degradation of RB5, the appropriate reaction parameters are at pH= 2, concentration of H2O2 = 60 mg/L. In terms of mineralization efficiency, NiFe2O4 (63%) is better than DS slag (23%) when reaction time was up to 24 hours. In ferrite application, sintered NiFe2O4 had higher intensity of crystallization with higher sintering temperature and longer retention time; they also showed better performance in decoloration of RB5 and in mineralization efficiency. Sintering temperature of 1000℃ and retention time of 10 hours were appropriate conditions of ferritization in generating Fenton-like reaction for degradation of RB5. Powder from ferritization of EPS could decolorize RB5 completely with Fenton-like reaction for 1 hour. After catalytic reaction, leaching of heavy metals in solution was insignificant. High-temperature ferritization not only could effectively stabilize heavy metals in EPS, but also had distinctive catalytic effect after clinkering.

As for material stabilization properties, ferrite particles synthesized from EPS degrading RB5 by Fenton-like reaction showed stability in RB5 removal even after 10 cycles of experiment, RB5 was completely decolorized after 6 hours of reaction time with high mineralization efficiency and only resulted in a small amount of Fe leaching. However, decoloration of RB5 using DS slag showed slightly lower removal efficiency than EPS synthetic ferrite, its mineralization efficiency decreased with increasing duplicate tests and released a large number of Fe element. It is concluded that DS slag and EPS synthetic ferrite were effective Fenton-like catalysts as well as environmental friendly renewed catalyst. Due to large number of Fe leaching and the high reaction rate of DS slag; it is recommended to apply DS slag in batch treatment or processing. Ferrite synthesized from EPS was stable during the reaction, and leaching of Fe was barely observed; thus it is a potential catalytic material that can be utilized in permeable catalytic barrier, it is recommended to apply in long-term pollutants treatment in situ.

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